Iontosorb AMD
For decomposition of pesticides and nerve-paralytic agents
IONTOSORB AMD is a specific reactive sorbent with cellulose matrix and amidoxime fixed to cellulose glucose units at their C-6 positions. IONTOSORB AMD is outstanding in highly effective removal of organophosphate pesticides and nerve-paralytic chemical warfare agents (CWAs).
Removal of organophosphate pesticides
Pesticide degradation by using IONTOSORB AMD proceeds with a half time 20 - 30 hours at pH about 7 - 7.5. Parathion methyl and paraoxon methyl degradation runs both in neutral and basic media. In acidic solutions, degradation constants decrease up to pH 6.
| Time dependencies for the pesticide degradation in the presence of the AMD reactive sorbent. a) parathion methyl, pH 5.02; b) parathion methyl, pH 7.22; c) parathion methyl, pH 9.00; d) paraoxon methyl, pH 7.22. The initial pesticide concentration was 20 mg/L, the buffer concentration was 0.05 mol/L and the concentration of sorbent was 12.5 g/L. |
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| Dependence of the degradation rate constants on pH (calculated from the rate of 4-nitrophenol creation) |
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Removal of nerve-paralytic chemical warfare agents
IONTOSORB AMD decomposes VX agent and soman with more than 90 % conversion during 1 hour so it belongs to the most efficient decontamination agents for this class of compounds.
| Degradation of nerve gases soman (a) and VX agent (b) in the presence of the AMD sorbent |
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Iontosorb AMD sorbent was developed in co-operation with Prof. Ing. Pavel Jano¹, CSc., Faculty of the Environment, University of Jan Evangelista Purkynì, Pasteurova 3544/1, 400 96 Ústí nad Labem, Czech Republic.
Tests with nerve-paralytic chemical warfare agents were done in Military Research Institute, Veslaøská 230, 637 00 Brno, Czech Republic.
Detailed infromation willl be published in the scientific article: P. Jano¹, O. Tokar, M. Do¹ek, K. Mazanec, P. Jano¹ junior: Amidoxime-functionalized bead cellulose for the decomposition of highly toxic organophosphates. Carbohydratre Polymers. In press.
